{"id":13654,"date":"2024-07-22T15:05:55","date_gmt":"2024-07-22T07:05:55","guid":{"rendered":"https:\/\/www.humicchina.com\/?p=13654"},"modified":"2025-06-26T12:07:07","modified_gmt":"2025-06-26T04:07:07","slug":"humic-acids-used-for-industrial-wastewater-treatment-application","status":"publish","type":"post","link":"https:\/\/www.humicchina.com\/tr\/blog\/humic-acids-used-for-industrial-wastewater-treatment-application.html","title":{"rendered":"End\u00fcstriyel At\u0131k Su Ar\u0131tma Uygulamalar\u0131nda Kullan\u0131lan Humik Asitler"},"content":{"rendered":"\r\n
\r\n

End\u00fcstriyel at\u0131k su ar\u0131tma \u00dcr\u00fcn\u00fc:\u00a0H\u00fcmik asitlerin suda \u00e7\u00f6z\u00fcn\u00fcr sodyum tuzu<\/a><\/p>\r\n\r\n\r\n\r\n

Su ar\u0131t\u0131m\u0131nda h\u00fcmik asit tuzlar\u0131 yakla\u015f\u0131k olarak kullan\u0131l\u0131r. Yakla\u015f\u0131k %10 sodyum i\u00e7eri\u011fine sahip %10 sulu \u00e7\u00f6zelti. %1.<\/p>\r\n\r\n\r\n\r\n

\u00c7\u00f6zeltinin pH de\u011feri 9 ila 10 aras\u0131ndad\u0131r. Hafif bulan\u0131kl\u0131k veya muhtemelen k\u00fc\u00e7\u00fck tortu, do\u011fal kil bile\u015fenlerinden kaynaklan\u0131r. H\u00fcmik asit tuzlar\u0131, \u00f6zel bir ekstraksiyon i\u015flemi kullan\u0131larak kahverengi k\u00f6m\u00fcr\u00fcn oksidasyon \u00fcr\u00fcn\u00fcnden \u00fcretilir. \u00dcr\u00fcn, n\u00f6trle\u015ftirme yoluyla kantitatif olarak \u00e7\u00f6keltilebilen veya p\u0131ht\u0131la\u015ft\u0131r\u0131labilen y\u00fcksek molek\u00fcll\u00fc h\u00fcmik asitlerden ve tercihen \u00e7ok de\u011ferlikli katyonlardan olu\u015fur. Su ar\u0131t\u0131m\u0131nda kullan\u0131lan h\u00fcmik asitler, zaman zaman su i\u015fleri operasyonlar\u0131ndan \u00f6zellikle y\u0131k\u0131c\u0131 yeralt\u0131 suyu kirleticileri olarak bilinen h\u00fcmik maddeler ve bunlar\u0131n metal kompleksleri ile kar\u0131\u015ft\u0131r\u0131lmamal\u0131d\u0131r. Bunlar d\u00fc\u015f\u00fck molek\u00fcll\u00fc h\u00fcmik maddeler veya h\u00fcmik madde \u00f6nc\u00fcleridir.<\/p>\r\n\r\n\r\n

\r\n
\"Humic-Acids-Used-for-Industrial-Wastewater-Treatment-Application\"<\/figure><\/div>\r\n\r\n\r\n

\u00d6zellikleri: P\u0131ht\u0131la\u015fm\u0131\u015f h\u00fcmik asitler a\u015fa\u011f\u0131daki bask\u0131n \u00f6zelliklere sahiptir:<\/p>\r\n\r\n\r\n\r\n

    \r\n
  1. Lipofilik maddelerin adsorpsiyonu<\/li>\r\n\r\n\r\n\r\n
  2. Elektron don\u00f6r\/al\u0131c\u0131 kompleksi olu\u015fumu<\/li>\r\n\r\n\r\n\r\n
  3. Bazlarla tuz olu\u015fumu<\/li>\r\n\r\n\r\n\r\n
  4. \u00c7ok de\u011ferlikli katyonlar ve a\u011f\u0131r metallerle az \u00e7\u00f6z\u00fcnen komplekslerin olu\u015fumu<\/li>\r\n\r\n\r\n\r\n
  5. Asitlerle tuz olu\u015fumu ve<\/li>\r\n\r\n\r\n\r\n
  6. Elektron de\u011fi\u015fim kapasitesi<\/li>\r\n<\/ol>\r\n\r\n\r\n\r\n

    Bu \u00f6zelliklerinden dolay\u0131 \u00f6zel h\u00fcmik asit tuzlar\u0131, \u00f6zellikle madde gruplar\u0131 olmak \u00fczere \u00e7e\u015fitli su kirleticileri i\u00e7in emici madde olarak uygundur.<\/p>\r\n\r\n\r\n\r\n

      \r\n
    1. A\u011f\u0131r metaller<\/li>\r\n\r\n\r\n\r\n
    2. Lipofilik maddeler.<\/li>\r\n<\/ol>\r\n\r\n\r\n\r\n

      End\u00fcstriyel at\u0131k su ar\u0131t\u0131m\u0131nda h\u00fcmik asit tuzlar\u0131n\u0131n \u00f6zellikle de\u011ferli bir \u00f6zelli\u011fi, suyun n\u00f6tr ila asidik pH aral\u0131\u011f\u0131nda p\u0131ht\u0131la\u015fma kapasiteleridir; bu, \u00f6zellikle kalsiyum, al\u00fcminyum veya demir gibi \u00e7ok de\u011ferlikli katyonlar\u0131n varl\u0131\u011f\u0131nda kaba pullar halinde \u00e7\u00f6kelmesine neden olur.<\/p>\r\n\r\n\r\n\r\n

      Etki spektrumu: Bahsedilen \u00f6zelliklerden dolay\u0131 h\u00fcmik asit tuzlar\u0131n\u0131n bu \u00f6zel formu su ar\u0131t\u0131m\u0131nda kullan\u0131l\u0131r. Bu ortamdan a\u011f\u0131r metallerin, \u00f6zellikle a\u015fa\u011f\u0131daki gibi eser d\u00fczeylere kadar uzakla\u015ft\u0131r\u0131lmas\u0131 i\u00e7in idealdirler:<\/p>\r\n\r\n\r\n\r\n

        \r\n
      1. Kromatlar<\/li>\r\n\r\n\r\n\r\n
      2. Nikel bile\u015fikleri<\/li>\r\n\r\n\r\n\r\n
      3. Bak\u0131r bile\u015fikleri<\/li>\r\n\r\n\r\n\r\n
      4. C\u0131va bile\u015fikleri<\/li>\r\n\r\n\r\n\r\n
      5. Kadmiyum bile\u015fikleri<\/li>\r\n\r\n\r\n\r\n
      6. Kur\u015fun bile\u015fikleri<\/li>\r\n\r\n\r\n\r\n
      7. \u00c7inko bile\u015fikleri<\/li>\r\n<\/ol>\r\n\r\n\r\n\r\n

        Ayr\u0131ca p\u0131ht\u0131la\u015fm\u0131\u015f h\u00fcmik asit tuzlar\u0131, y\u00fcksek i\u00e7 y\u00fczeyleri nedeniyle lipofilik organik bile\u015fenleri sorpsiyon yoluyla ba\u011flayabilir. \u00c7\u00f6keltilmi\u015f h\u00fcmik asit tuzlar\u0131n\u0131n p\u0131ht\u0131la\u015ft\u0131r\u0131c\u0131 \u00f6zelliklerinden dolay\u0131 \u00e7ak\u0131l filtrasyonu i\u00e7in topakla\u015ft\u0131r\u0131c\u0131 veya \u00f6n kaplama olarak da kullan\u0131labilirler. Bu \u00f6zellikleri nedeniyle h\u00fcmik asit tuzlar\u0131, at\u0131k su ve maden suyunun ar\u0131t\u0131lmas\u0131nda \u00e7e\u015fitli \u015fekillerde kullan\u0131labilir.<\/p>\r\n\r\n\r\n\r\n

        Ba\u015fvuru:<\/p>\r\n\r\n\r\n\r\n

        H\u00fcmik asit tuzu \u00e7\u00f6zeltisi, geleneksel topakla\u015ft\u0131r\u0131c\u0131lar\u0131n dozaj\u0131nda \u200b\u200bda yayg\u0131n oldu\u011fu gibi, dozaj sistemleri kullan\u0131larak ar\u0131t\u0131lacak at\u0131k su ile kar\u0131\u015ft\u0131r\u0131l\u0131r. At\u0131k suyun, tercihen kalsiyum klor\u00fcr, al\u00fcminyum veya demir tuzlar\u0131 olmak \u00fczere \u00e7ok de\u011ferlikli katyonlar\u0131n e\u015f zamanl\u0131 eklenmesiyle n\u00f6trle\u015ftirilmesiyle 7,5’in alt\u0131ndaki pH de\u011ferlerinde p\u0131ht\u0131la\u015ft\u0131r\u0131l\u0131r. Bu, yaln\u0131zca yukar\u0131da belirtilen \u00e7\u00f6zelti y\u00fck\u00fcn\u00fc emme yoluyla ba\u011flamakla kalmay\u0131p, ayn\u0131 zamanda ask\u0131da kalan madde y\u00fck\u00fcn\u00fc geleneksel yolla p\u0131ht\u0131la\u015ft\u0131rabilen ve b\u00f6ylece suyun ar\u0131t\u0131lmas\u0131n\u0131 sa\u011flayan tipik h\u00fcmik asit topaklar\u0131 olu\u015fturur. H\u00fcmik asit tuzlar\u0131 geleneksel topakla\u015ft\u0131r\u0131c\u0131larla kombinasyon halinde \u00f6zellikle avantajl\u0131d\u0131r. Bunlar genellikle eklenen h\u00fcmik asit tuzu \u00e7\u00f6zeltisi ile n\u00f6tralize edilen asitlere hidrolize olur. Bu, etkili bir \u015fekilde \u00e7\u00f6keltilebilen veya filtrelenebilen \u00e7ok kararl\u0131 bir birle\u015fik topaklanma olu\u015fturur.<\/p>\r\n\r\n\r\n\r\n

        End\u00fcstriyel at\u0131k su ar\u0131t\u0131m\u0131nda \u00f6zel avantajlar:<\/p>\r\n\r\n\r\n\r\n

          \r\n
        1. \u00c7\u00f6z\u00fcnm\u00fc\u015f a\u011f\u0131r metallerin ayr\u0131lmas\u0131<\/li>\r\n\r\n\r\n\r\n
        2. \u00c7\u00f6z\u00fcnm\u00fc\u015f lipofilik maddelerin ayr\u0131lmas\u0131<\/li>\r\n\r\n\r\n\r\n
        3. Kat\u0131 ya\u011flar, s\u0131v\u0131 ya\u011flar ve her t\u00fcrl\u00fc ask\u0131daki madde i\u00e7in etkili topakla\u015ft\u0131r\u0131c\u0131<\/li>\r\n\r\n\r\n\r\n
        4. Geleneksel topakla\u015ft\u0131r\u0131c\u0131lar\u0131n etkinli\u011finin artt\u0131r\u0131lmas\u0131 ve ayn\u0131 zamanda alkalin n\u00f6trle\u015ftirme maddesi olarak g\u00f6rev yapmas\u0131<\/li>\r\n\r\n\r\n\r\n
        5. A\u011f\u0131r metallerin ve lipofillerin immobilizasyonu yoluyla ar\u0131tma \u00e7amuru \u00f6zelliklerinin iyile\u015ftirilmesi<\/li>\r\n<\/ol>\r\n\r\n\r\n\r\n
          \"Special<\/figure>\r\n\r\n\r\n\r\n

          B\u00f6ylece:<\/p>\r\n\r\n\r\n\r\n

            \r\n
          1. Ar\u0131tma \u00e7amurunun do\u011fal toprak g\u00f6zenek yap\u0131s\u0131 olu\u015fturularak tar\u0131mda kullan\u0131ma uygun hale getirilmesi<\/li>\r\n\r\n\r\n\r\n
          2. H\u00fcmik asitler bir\u00e7ok ekosistem i\u00e7in gerekli bir do\u011fal maddedir<\/li>\r\n<\/ol>\r\n\r\n\r\n\r\n

            \u00d6rnek:<\/p>\r\n\r\n\r\n\r\n

            At\u0131k yakma tesisinden \u00e7\u0131kan baca gaz\u0131n\u0131n temizlenmesi: Baca gaz\u0131 su d\u00f6ng\u00fcs\u00fcnden s\u00fcrekli olarak y\u00f6nlendirilen ve at\u0131k su olarak de\u015farj edilen suyun, de\u015farjdan \u00f6nce ar\u0131t\u0131lmas\u0131 gerekir. Genellikle a\u011f\u0131r metal i\u00e7eri\u011fi y\u00fcksek olan su genellikle y\u00fcksek oranda asidiktir ve bu nedenle n\u00f6tralize edilmesi gerekir. A\u011f\u0131r metal ay\u0131rmaya y\u00f6nelik geleneksel i\u015flemler, a\u011f\u0131r metallerin alkalin pH aral\u0131\u011f\u0131nda hidroksitler halinde \u00e7\u00f6keltilmesi i\u00e7in alkali ile i\u015fleme tabi tutulmas\u0131na dayan\u0131r. Bu \u00e7\u00f6kt\u00fcrme i\u015flemi ba\u015fta c\u0131va olmak \u00fczere baz\u0131 a\u011f\u0131r metaller i\u00e7in yeterli de\u011fildir.<\/p>\r\n\r\n\r\n

            \r\n
            \"Flue<\/figure><\/div>\r\n\r\n\r\n

            Di\u011fer bir dezavantaj ise at\u0131k suyun alkalin pH de\u011feridir ve bunun daha sonraki bir n\u00f6trle\u015ftirme a\u015famas\u0131nda d\u00fczeltilmesi gerekir. Baca gaz\u0131 temizleme i\u015fleminden gelen at\u0131k suya ortak n\u00f6tralizasyon maddesi olarak h\u00fcmik asit tuzu \u00e7\u00f6zeltisi eklenerek (gerekirse kire\u00e7 ve geleneksel topakla\u015ft\u0131r\u0131c\u0131lar\u0131n yan\u0131 s\u0131ra demir tuzlar\u0131 ve muhtemelen organik polielektrolit ile kombinasyon halinde). Geleneksel alkali \u00e7\u00f6keltme i\u015flemiyle kar\u015f\u0131la\u015ft\u0131r\u0131ld\u0131\u011f\u0131nda, n\u00f6tr ila hafif asidik pH aral\u0131\u011f\u0131ndaki a\u011f\u0131r metal i\u00e7eri\u011fi h\u00fcmik asit ile niceliksel olarak ayr\u0131labilir. End\u00fcstriyel at\u0131k su ar\u0131t\u0131m\u0131nda tuzlanman\u0131n en aza indirilmesi gibi ek bir avantaja sahiptir.<\/p>\r\n\r\n\r\n\r\n

            Bertaraf H\u00fcmik asitlerdeki a\u011f\u0131r metallerin s\u0131k\u0131 ba\u011flanmas\u0131ndan dolay\u0131, normalde bu elemanlar\u0131n hareketlili\u011fine yol a\u00e7abilecek ko\u015fullar alt\u0131nda bile bu bile\u015fenlerin kanalizasyon \u00e7amurundan sal\u0131nmas\u0131 beklenmez. \u00f6rne\u011fin \u00f6zellikle \u00e7\u00f6ken hidroksitten a\u011f\u0131r metal hareketlili\u011fine yol a\u00e7abilen asidik \u00e7\u00f6keltme yoluyla.<\/p>\r\n\r\n\r\n\r\n

            Topra\u011f\u0131n iyile\u015ftirilmesi i\u00e7in tar\u0131msal kullan\u0131m gibi daha \u00f6nce sorunlu olan imha yollar\u0131 b\u00f6ylece daha g\u00fcvenli bir \u015fekilde takip edilebilir. Ar\u0131tma \u00e7amurunda bulunan lipofilik kirleticiler, \u00f6r. aromatik polisiklikler, poliklorlu bifeniller, dioksinler ve furanlar h\u00fcmik asitler taraf\u0131ndan immobilize edilir. End\u00fcstriyel at\u0131k su ar\u0131t\u0131m\u0131nda veya \u00e7amur ar\u0131t\u0131m\u0131nda h\u00fcmik asitlerin kullan\u0131lmas\u0131 tam da bu nedenle avantajl\u0131d\u0131r.<\/p>\r\n\r\n\r\n\r\n

            H\u00fcmik asit i\u00e7eren kanalizasyon \u00e7amuru bu nedenle tar\u0131msal kullan\u0131m i\u00e7in benzer geleneksel kanalizasyon \u00e7amuruna g\u00f6re \u00e7ok daha uygundur, \u00e7\u00fcnk\u00fc p\u0131ht\u0131la\u015fm\u0131\u015f h\u00fcmik asitler kurutulmu\u015f \u00e7amura ve dolay\u0131s\u0131yla \u00e7amurla i\u015flenen topra\u011fa ufalanabilir, topraks\u0131-humik bir k\u0131vam verir, bu da topra\u011f\u0131n bir bitki substrat\u0131 olarak i\u015flevini bir\u00e7ok y\u00f6nden geli\u015ftirebilir (havaland\u0131rma, nem tutma, r\u00fczgar ta\u015f\u0131nmas\u0131na kar\u015f\u0131 diren\u00e7, g\u00fcbre tutma, topra\u011f\u0131n nitrat, amonyum ve biyositlere kar\u015f\u0131 ge\u00e7irgenli\u011finin azalt\u0131lmas\u0131).<\/p>\r\n\r\n\r\n\r\n

            Aksi takdirde h\u00fcmik asit i\u00e7eren \u00e7amur, kurutulduktan sonra a\u015fa\u011f\u0131daki gibi termal i\u015flemlerde enerji kayna\u011f\u0131 olarak kullan\u0131labilir:<\/p>\r\n\r\n\r\n\r\n

              \r\n
            1. at\u0131k yakma<\/li>\r\n\r\n\r\n\r\n
            2. at\u0131k gazla\u015ft\u0131rma<\/li>\r\n\r\n\r\n\r\n
            3. at\u0131k pirolizi<\/li>\r\n\r\n\r\n\r\n
            4. di\u011fer yakma tesislerinde ilave yak\u0131t<\/li>\r\n\r\n\r\n\r\n
            5. \u00e7imento \u00fcretimi<\/li>\r\n<\/ol>\r\n\r\n\r\n\r\n

              A\u011f\u0131r metal i\u00e7eri\u011finin tercihen \u00e7evre dostu bir \u015fekilde c\u00fcruf eriyi\u011finde veya \u00e7imento klinkerinde (her ikisi de ayn\u0131 zamanda in\u015faat end\u00fcstrisi i\u00e7in hammadde olan) silikat ba\u011flamada sabitlendi\u011fi durumlarda.<\/p>\r\n\r\n\r\n\r\n

              End\u00fcstriyel at\u0131k su ar\u0131tma \u00fcr\u00fcn bilgileri:<\/p>\r\n\r\n\r\n\r\n

                \r\n
              1. H\u00fcmik asit tuzlar\u0131n\u0131n \u00f6zellikleri\r\n
                  \r\n
                • G\u00f6r\u00fcn\u00fcm: siyah-kahverengi suda \u00e7\u00f6z\u00fcn\u00fcr toz veya pullar<\/strong><\/li>\r\n\r\n\r\n\r\n
                • Koku: kokusuz<\/strong><\/li>\r\n\r\n\r\n\r\n
                • Aktif madde: sodyum tuzu formundaki h\u00fcmik asitler<\/strong><\/li>\r\n\r\n\r\n\r\n
                • CAS Numaras\u0131: 68131-04-4<\/strong><\/li>\r\n\r\n\r\n\r\n
                • pH de\u011feri: 9-10<\/strong><\/li>\r\n<\/ul>\r\n<\/li>\r\n\r\n\r\n\r\n
                • Toksikoloji ve ekoloji Temizlenecek at\u0131k su ile kar\u0131\u015ft\u0131r\u0131l\u0131p n\u00f6tralize edildikten sonra, yaln\u0131zca kullan\u0131lan h\u00fcmik asit \u00e7\u00f6zeltisinin alkalinitesinden kaynaklanan olas\u0131 olumsuz ekolojik veya toksik etkiler ortadan kald\u0131r\u0131l\u0131r. H\u00fcmik asitler tamamen zarars\u0131z do\u011fal bir madde oldu\u011fundan kendi ba\u015flar\u0131na herhangi bir olumsuz etkisi yoktur.<\/li>\r\n\r\n\r\n\r\n
                • Depolama ve ta\u015f\u0131ma Kaplar \u0131s\u0131 veya donma gibi a\u015f\u0131r\u0131 dalgalanmalara maruz b\u0131rak\u0131lmad\u0131\u011f\u0131 ve kuru olarak depoland\u0131\u011f\u0131 takdirde, h\u00fcmik asit tuzlar\u0131n\u0131n depolama stabilitesi neredeyse s\u0131n\u0131rs\u0131zd\u0131r. Ciltteki kirleticiler sabun ve su ile temizlenebilir. G\u00f6ze temas\u0131 halinde derhal bol temiz su ile y\u0131kay\u0131n\u0131z.<\/li>\r\n\r\n\r\n\r\n
                • Ta\u015f\u0131ma y\u00f6netmelikleri Y\u00fcr\u00fcrl\u00fckteki ulusal ve uluslararas\u0131 ta\u015f\u0131ma y\u00f6netmeliklerine g\u00f6re tehlikeli bir madde de\u011fildir.<\/li>\r\n<\/ol>\r\n<\/div><\/div>\r\n\r\n\r\n\r\n

                   <\/p>\r\n","protected":false},"excerpt":{"rendered":"

                  Industrial wastewater treatment Product:Water-soluble sodium salt of humic acids
                  \nHumic acid salts for water treatment are used as an approx. 10% aqueous solution with a sodium content of approx. 1%.<\/p>\n","protected":false},"author":1,"featured_media":13695,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_yoast_wpseo_title":"Humic Acids Used for Industrial Wastewater Treatment %%page%% %%sep%% JINGFENG","_yoast_wpseo_metadesc":"The strong chelation of industrial wastewater treatment humic acids can be an effective and environmentally-friendly 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